Poly[[bis(μ2-4-aminobenzenesulfonato-κ2 N:O)diaquamanganese(II)] dihydrate]
نویسندگان
چکیده
The title compound, {[Mn(NH(2)C(6)H(4)SO(3))(2)(H(2)O)(2)]·2H(2)O}(n), was prepared under mild hydro-thermal conditions. The unique Mn(II) ion is located on a crystallographic inversion center and is coordinated by two -NH(2) and two -SO(3) groups from four 4-amino-benzene-sulfonate ligands and by two water mol-ecules in the axial positions, forming a slightly distorted octa-hedral coordination environment. The 4-amino-benzene-sulfonate anions behave as μ(2)-bridging ligands to produce a two-dimensional structure. In the crystal structure, inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds link the layers into a three-dimensional network.
منابع مشابه
catena-Poly[[diaquamanganese(II)]-di-μ-pyridine-3-sulfonato-κ2 N:O;κ2 O:N]
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